Dicobalt copper bis[orthophosphate(V)] monohydrate, Co2.39Cu0.61(PO4)2·H2O
Identifieur interne : 000569 ( Main/Exploration ); précédent : 000568; suivant : 000570Dicobalt copper bis[orthophosphate(V)] monohydrate, Co2.39Cu0.61(PO4)2·H2O
Auteurs : Abderrazzak Assani [Maroc] ; Mohamed Saadi [Maroc] ; Lahcen El Ammari [Maroc]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
In an attempt to hydrothermally synthesize a phase with composition Co2Cu(PO4)2·H2O, we obtained the title compound, Co2.39Cu0.61(PO4)2·H2O instead. Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO6 octahedra, (Cu/Co)O5 square pyramids and PO4 tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O5 square pyramids linked
Url:
DOI: 10.1107/S1600536810015382
PubMed: 21578990
PubMed Central: 2979060
Affiliations:
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Le document en format XML
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Chemical analysis confirmed the presence of copper in the crystal. The crystal structure of the title compound can be described as a three- dimensional network constructed from the stacking of two types of layers extending parallel to (010). These layers are made up from more or less deformed polyhedra: CoO<sub>6</sub> octahedra, (Cu/Co)O<sub>5</sub> square pyramids and PO<sub>4</sub> tetrahedra. The first layer is formed by pairs of edge-sharing (Cu/Co)O<sub>5</sub> square pyramids linked <italic>via</italic> a common edge of each end of the (Cu/Co)<sub>2</sub>O<sub>8</sub> dimer to PO<sub>4</sub> tetrahedra. The second layer is undulating and is built up from edge-sharing CoO<sub>6</sub> octahedra. The linkage between the two layers is accomplished by PO<sub>4</sub> tetrahedra. The presence of water molecules in the CoO<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub> octahedron also contributes to the cohesion of the layers through O—H⋯O hydrogen bonding.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct><biblStruct></biblStruct></listBibl></div1></back></TEI><affiliations><list><country><li>Maroc</li></country></list><tree><country name="Maroc"><noRegion><name sortKey="Assani, Abderrazzak" sort="Assani, Abderrazzak" uniqKey="Assani A" first="Abderrazzak" last="Assani">Abderrazzak Assani</name></noRegion><name sortKey="El Ammari, Lahcen" sort="El Ammari, Lahcen" uniqKey="El Ammari L" first="Lahcen" last="El Ammari">Lahcen El Ammari</name><name sortKey="Saadi, Mohamed" sort="Saadi, Mohamed" uniqKey="Saadi M" first="Mohamed" last="Saadi">Mohamed Saadi</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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